Bis(propane-1,3-diaminium) hexafluoridoferrate(III) fluoride trihydrate

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Bis(propane-1,3-diaminium) hexa­fluoridoferrate(III) fluoride trihydrate

The asymmetric unit of the title iron hybrid fluoride, (C(3)H(12)N(2))(2)[FeF(6)]F·3H(2)O, contains two propane-1,3-diamin-ium [(H(2)dap)(2+)] cations, an octa-hedral [FeF(6)](3-) anion, an isolated F(-) anion and three water mol-ecules of solvation. Each [FeF(6)](3-) anion is surrounded by four separate hydrogen-bonded water mol-ecules in the equatorial sites and by five separate aminium catio...

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Crystal structure of bis­(propane-1,3-di­ammonium) hexa­fluorido­aluminate fluoride trihydrate

The title compound, (C3H10N2)2[AlF6]F·3H2O, was obtained using the solvothermal method with aluminium hydroxide, HF and propane-1,3-di-amine as precursors in ethanol as solvent. The structure consists of isolated [AlF6](3-) octa-hedra, diprotonated propane-1,3-di-amine cations [(H2dap)(2+)], free fluoride ions and water mol-ecules of solvation. The Al-F bond lengths in the octa-hedral [AlF6](3-...

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Propane-1,2-diaminium tris­(pyridine-2,6-dicarboxyl­ato-κ3 O 2,N,O 6)zirconate(IV) trihydrate

In the title compound, (C(3)H(12)N(2))[Zr(C(7)H(3)NO(4))(3)]·3H(2)O, the Zr(IV) cation is chelated by three pyridine-2,6-dicarboxyl-ate anions in a distorted tricapped trigonal-prismatic environment. The crystal structure is stabilized by inter-molecular N-H⋯O and O-H⋯O hydrogen bonds.

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Decane-1,10-diaminium dinitrate

The crystal structure of the title compound, C(10)H(26)N(2) (2+)·2NO(3) (-), exhibits a back-to-back paired double-stacked packing arrangement culminating in an overall double zigzag pattern of the dications. Each pair of double-stacked dications is surrounded by a ring of ten nitrate anions. An intricate three-dimensional N---H...O and N---H...(O,O) hydrogen-bonding network exists in the cryst...

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Heptane-1,7-diaminium dinitrate

In the title molecular salt, C(7)H(20)N(2) (2+)·2NO(3) (-), the crystal structure exhibits an unusual back-to-back paired double-stacked packing arrangement culminating in an overall double zigzag pattern of the dications. The nitrate anions form a ring around one pair of double-stacked dications. An intricate three-dimensional N-H⋯O and N-H⋯(O,O) hydrogen-bonding network exists in the crystal ...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810018039